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Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

The possibilities for extending the range of engine loads in which soot and NOx emissions can be minimised by using low temperature combustion in conjunction with high levels of EGR was investigated in a series of experiments with a single cylinder research engine. The results show that very low levels of both soot and NOx emissions can be achieved at engine loads up to 50 % by reducing the compression ratio to 14 and applying high levels of EGR (up to approximately 60 %). Unfortunately, the low temperature combustion is accompanied by increases in fuel consumption and emissions of both HC and CO. However, these drawbacks can be reduced by advancing the injection timing. The research engine was a 2 litre direct injected (DI), supercharged, heavy duty, single cylinder diesel engine with a geometry based on Volvo's 12 litre engine, and the amount of EGR was increased by adjusting the exhaust back pressure while keeping the charge air pressure constant.

In this paper a fast NOx model is presented which can be used for engine optimization, aftertreatment control or virtual mapping. A cylinder pressure trace is required as input data. High calculation speed is obtained by using table interpolation to calculate equilibrium temperatures and species concentrations. Test data from a single-cylinder engine and from a complete six-cylinder engine have been used for calibration and validation of the model. The model produces results of good agreement with emission measurements using approximately 50 combustion product zones and a calculation time of one second per engine cycle. Different compression ratios, EGR rates, injection timing, inlet pressures etc. were used in the validation tests.

High-speed laser diagnostics was utilized for single-cycle resolved studies of the formaldehyde distribution in the combustion chamber of an HCCI engine. A multi-YAG laser system consisting of four individual Q-switched, flash lamp-pumped Nd:YAG lasers has previously been developed in order to obtain laser pulses at 355 nm suitable for performing LIF measurements of the formaldehyde molecule. Bursts of up to eight pulses with very short time separation can be produced, allowing capturing of LIF image series with high temporal resolution. The system was used together with a high-speed framing camera employing eight intensified CCD modules, with a frame-rate matching the laser pulse repetition rate. The diagnostic system was used to study the combustion in a truck-size HCCI engine, running at 1200 rpm using n-heptane as fuel. By using laser pulses with time separations as short as 70 μs, cycle-resolved image sequences of the formaldehyde distribution were obtained.

This paper is a study of the effects of valve timing and how it influences the in-cylinder fluid flow, the combustion, and the efficiency of the engine. An engine load of 4.0 bar imepnet was achieved by setting the inlet valve closing time early or late to enable unthrottled operation. Inlet valve deactivation was also used and asymmetrical valve timing, i.e. valve timing with the two inlet valves opening and closing at different times. The valve timing was altered by switching cam lobes between the experiments. The results indicate a longer flame development period but a faster combustion with early inlet valve closing compared to the throttled case. For late inlet valve closing, a variation in the combustion duration results. As expected, the pumping mean effective pressure (PMEP) was greatly reduced with early and late inlet valve closing compared to the throttled case.

The Homogeneous Charge Compression Ignition (HCCI) is the third alternative for combustion in the Internal Combustion (IC) engines. Here, a homogeneous charge is used as in a spark ignited engine but the charge is compressed to auto-ignition as in a diesel. The characteristics of HCCI were compared to SI using a 1.6 liter single cylinder engine with compression ratio 21:1 in HCCI mode and 12:1 in SI mode. Three different fuels were used; isooctane, ethanol and natural gas. Some remarkable results were noted in the experiments: The indicated efficiency of HCCI was much better than for SI operation. Very little NOx was generated with HCCI, eliminating the need for a LeanNOx catalyst. However, HCCI generated more HC and CO than SI operation. Stable and efficient operation with HCCI could be obtained with λ=3 to λ=9 using isooctane or ethanol. Natural gas, with a higher octane number, required a richer mixture to run in HCCI mode.

Heavy trucks contribute significantly to the overall air pollution, especially NOx and PM emissions. Models to predict the emissions from heavy trucks in real world on road conditions are therefore of great interest. Most such models are based on data achieved from stationary measurements, i.e. engine maps. This type of “quasi stationary” models could also be of interest in other applications where emission models of low complexity are desired, such as engine control and simulation and control of exhaust aftertreatment systems. In this paper, results from quasi stationary calculations of fuel consumption, CO, HC, NOx and PM emissions are compared with time resolved measurements of the corresponding quantities. Measurement data from three Euro 3-class engines is used. The differences are discussed in terms of the conditions during transients and correction models for quasi stationary calculations are presented. Simply using engine maps without transient correction is not sufficient.

The main benefit of HCCI engines compared to SI engines is improved fuel economy. The drawback is the diluted combustion with a substantially smaller operating range if not some kind of supercharging is used. The reasons for the higher brake efficiency in HCCI engines can be summarized in lower pumping losses and higher thermodynamic efficiency, due to higher compression ratio and higher ratio of specific heats if air is used as dilution. In the low load operating range, where HCCI today is mainly used, other parameters as friction losses, and cooling losses have a large impact on the achieved brake efficiency. To initiate the auto ignition of the in-cylinder charge a certain temperature and pressure have to be reached for a specific fuel. In an engine with high in-cylinder cooling losses the initial charge temperature before compression has to be higher than on an engine with less heat transfer.

Turbulent premixed natural gas - air flame velocities have been measured in a stationary axi-symmetric burner using LDA. The flame was stabilized by letting the flow retard toward a stagnation plate downstream of the burner exit. Turbulence was generated by letting the flow pass through a plate with drilled holes. Three different hole diameters were used, 3, 6 and 10 mm, in order to achieve different turbulent length scales. Turbulent integral length scales were measured using two-point LDA and the stretching in terms of the Karlovitz number could be estimated from these measurements. The results support previous studies indicating that stretching reduces the flame speed.

The most economical way to convert truck and bus DI-diesel engines to natural gas operation is to replace the injector with a spark plug and modify the combustion chamber in the piston crown for spark ignition operation. The modification of the piston crown should give a geometry well suited for spark ignition operation with the original swirling inlet port. Ten different geometries were tried on a converted VOLVO TD102 engine and a remarkably large difference in the rate of combustion was noted between the chambers. To find an explanation for this difference a cycle resolved measurement of the in-cylinder mean velocity and turbulence was performed with Laser Doppler Velocimetry (LDV). The results show a high correlation between in cylinder turbulence and rate of heat release in the main part of combustion.

2D-LDV-measurements were made on the flow from one transfer channel into the cylinder in a small two-stroke SI engine. The LDV measuring volume was located just outside the transfer port. The engine was a carburetted piston-ported crankcase compression chainsaw engine and it was run with wide open throttle at 9000 RPM. The muffler was removed to enable access into the cylinder. No additional seeding was used; the fuel and/or oil was not entirely vaporized as it entered the cylinder. Very high velocities (-275 m/s) were detected in the beginning of the scavenging phase. The horizontal velocity was, during the whole scavenging phase, higher than the vertical.

The objective of this paper is to investigate how the combustion chamber design will influence combustion parameters and emissions in a natural gas SI engine. Ten different geometries were tried on a converted Volvo TD102 engine. For the different combustion chambers emissions and the pressure in the cylinder have been measured. The pressure in the cylinder was then used in a one-zone heat-release model to get different combustion parameters. The engine was operated unthrottled at 1200 rpm with different values of air/fuel ratio and EGR. The air/fuel ratio was varied from stoichiometric to lean limit. EGR values from 0 to 30% at stoichiometric air/fuel ratio were used. The results show a remarkably large difference in the rate of combustion between the chambers. The cycle-to-cycle variations are fairly independent of combustion chamber design as long as there is some squish area and the air and the natural gas are well mixed.

To study the effect of different injection timings on the charge inhomogeneity, planar laser-induced fluorescence (PLIF) was applied to an operating engine. Quantitative images of the fuel distribution within the engine were obtained. Since the fuel used, iso-octane, does not fluoresce, a dopant was required. Three-pentanone was found to have vapour pressure characteristics similar to those of iso-octane as well as low absorption and suitable spectral properties. A worst case estimation of the total accuracy from the PLIF images gives a maximum error of 0.03 in equivalence ratio. The results show that an early injection timing gives a higher degree of charge inhomogeneity close to the spark plug. It is also shown that charge inhomogeneity gives a more unstable engine operation. A correlation was noted between the combustion on a cycle to cycle basis and the average fuel concentration within a circular area close to the spark plug center.

2-D LDV measurements were performed on two different cylinder designs in a fired two-stroke engine running with wide-open throttle at 9000 rpm. The cylinders examined were one with open transfer channels and one with cup handle transfer channels. Optical access to the cylinder was achieved by removing the silencer and thereby gain optical access through the exhaust port. No addition of seeding was made, since the fuel droplets were not entirely vaporized as they entered the cylinder and thus served as seeding. Results show that the loop-scavenging effect was poor with open transfer channels, but clearly detectable with cup handle channels. The RMS-value, “turbulence”, was low close to the transfer ports in both cylinders, but increased rapidly in the middle of the cylinder. The seeding density was used to obtain information about the fuel concentration in the cylinder during scavenging.

The different roles played by small and large eddies in engine combustion were studied. Experiments compared natural gas combustion in a converted, single cylinder Volvo TD 102 engine and in a 125 mm cubical cell. Turbulence is used to enhance flame growth, ideally giving better efficiency and reduced cyclic variation. Both engine and test cell results showed that flame growth rate correlated best with the level of high frequency, small eddy turbulence. The more effective, small eddy turbulence also tended to lower cyclic variations. Large scales and bulk flows convected the flame relative to cool surfaces and were most important to the initial flame kernel.

The influence of residual gases on the cycle-to-cycle variations in engine combustion was investigated. Two-photon planar laser-induced fluorescence was used for 2D-visualization of residual gas water. In order to avoid influence from fuel fluorescence and inhomogeneities premixed natural gas was used as fuel. Measurements were conducted at different load conditions with varying inlet manifold pressure. To find out how the residual gas distribution influences the combustion process the pressure development during combustion was monitored. From the pressure information a measure of the combustion rate at different phases of the flame development was calculated. The correlation between residual gas distribution and combustion rate was evaluated on a cycle to cycle basis. The results show that with an inlet manifold pressure of 0.3 bar the correlation between residual gas fraction and rate of combustion were 0.5-0.6. At full load though, lower correlation was found.

This study is focused on the effect of different valve strategies on the in-cylinder flow and combustion A conventional four-valve pentroof engine was modified to enable optical access to the combustion chamber To get information on the flow, a two-component LDV system was applied The combustion was monitored by the use of cylinder pressure in a one-zone heat release model The results show that the flow in the cylinder with the valves operating in the standard configuration has an expected tumble characteristic In this case the high frequency turbulence is homogeneous and has a peak approximately 20 CAD BTDC With one valve deactivated, the flow shows a swirling pattern The turbulence is then less homogeneous but the level of turbulence is increased When the single inlet valve was phased late against the crankshaft dramatic effects on the flow resulted The late inlet valve opening introduced a low cylinder pressure before the valve opened The high pressure difference across the valve introduced a high-velocity jet into the cylinder Turbulence was increased by a factor of two by this operational mode When two inlet valves were used, a reduction of turbulence resulted from a very late inlet cam phase

In order to separate the HC-emissions from two-stroke engines into short-circuit losses and emissions due to incomplete combustion, Laser Induced Fluorescence (LIF) measurements were performed on the exhaust gases just outside the exhaust ports of two engines of different designs. The difference between the two engines was the design of the transfer channels. One engine had “finger” transfer channels and one had “cup handle” transfer channels. Apart from that they were similar. The engine with “finger” transfer channels was earlier known to give more short-circuiting losses than the other engine, and that behavior was confirmed by these measurements. Generally, the results show that the emission of hydrocarbons has two peaks, one just after exhaust port opening and one late in the scavenging phase. The spectral information shows differences between the two peaks and it can be concluded that the latter peak is due to short-circuiting and the earlier due to incomplete combustion.

The object of this paper is to present a new way of analyzing in-cylinder velocity measurements. The technique is called Discrete Wavelet Transform (DWT) and it is similar to Fast Fourier Transform (FFT) with one important difference it is possible to obtain both time localized and frequency resolved information. This paper demonstrates the use of DWT calculations on in-cylinder LDV flow measurements for different combustion geometries in a natural gas converted truck engine. It will furthermore provide some information about how DWT can be used with in-cylinder measurements in the future.

The influence of variable air-fuel ratio inside a spark ignition engine is examined by the use of an ionization sensor. The measured ion currents are used for predicting the local air-fuel ratio in the vicinity of the spark plug. In order to support the results, a theoretical analysis has been made. An instationary chemical kinetic model burning a mixture of iso-octane and n-heptane is used for the calculations. The results are used to reconstruct the crank angle resolved ion current that has been measured in an engine. This technique has been developed in order to offer a supplementary low-cost facility of controlling the air-fuel ratio within the combustion chamber of an engine.